Phase diagram, thermodynamic studies, and ab-initio calculations of the Ge-Li system was written by Gierlotka, W.;Debski, A.;Zabrocki, M.;Goral, A.;Gasior, W.. And the article was included in Journal of Chemical Thermodynamics in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:
The limiting enthalpy of solution of liquid germanium in the liquid tin ΔsolH∞Ge(l) was measured at 927 K and equals 3.24 ± 0.34 kJ/mol at. The standard enthalpy of formation of intermetallic phases from the Ge-Li system were calculated at 747 K with the use of the solution calorimetric method. These alloys and intermetallic phases were prepared from pure, metallic germanium and lithium, which were melted in a glove-box filled with high purity argon with a very low concentration of impurities. The X-ray diffraction measurements were conducted to verify the structure of the prepared alloys. The electromotive force studies were performed at three temperatures: 634 K, 807 K, and 841 K by the titration technique. Based on obtained results and other thermodn. quantities available in the literature the thermodn. properties of phases were optimized, and the Ge-Li phase diagram was determined This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics