Isoprene Soya Diels-Alder Adduct and Epoxidation for Photopolymerization was written by Ren, Xiaofeng;Xu, Tong;Thomas, Jomin;Soucek, Mark D.. And the article was included in Macromolecular Chemistry and Physics in 2021.Category: chlorides-buliding-blocks The following contents are mentioned in the article:
A novel cyclohexane derivatized soybean oil (CSO) is synthesized by Diels-Alder cycloaddition of soybean oil with isoprene. Then, the epoxidized cycloaliphatic soybean oil (ECSO) is prepared via epoxidation of CSO. For comparison purpose, norbornylized soybean oil (NSO) and epoxy norbornane soybean oil (ENSO) are synthesized. The CSO, ECSO, NSO, and ENSO are characterized by 1H NMR, 13C NMR, gradient heteronuclear single quantum correlation (gHSQC) 2D NMR, and mass spectroscopy. The epoxidized soybean oil (ESO), ECSO, and ENSO are photopolymerized using UV-light, and the kinetics of the photocuring reactions is evaluated by real-time Fourier transform IR (FT-IR) and photo-differential scanning calorimetry (DSC). Real-time FT-IR and photo-DSC indicate the improved reactivity of ECSO and ENSO compared to ESO. It is found that the curing rate and final conversion of novel developed ECSO is higher than ESO, but lower than ENSO. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Category: chlorides-buliding-blocks).
N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics