Exfoliation of Al-residual multilayer MXene using tetramethylammonium bases for conductive film applications was written by Saita, Emi;Iwata, Masaki;Shibata, Yuki;Matsunaga, Yuki;Suizu, Rie;Awaga, Kunio;Hirotani, Jun;Omachi, Haruka. And the article was included in Frontiers in Chemistry (Lausanne, Switzerland) in 2022.Synthetic Route of C4H12ClN The following contents are mentioned in the article:
This study describes the concise exfoliation of multilayer Ti3C2Tx MXene containing residual aluminum atoms. Treatment with tetramethylammonium base in a co-solvent of THF and H2O produced single-layer Ti3C2Tx, which was confirmed via at. force microscopy observations, with an elec. conductivity 100+ times that of Ti3C2Tx prepared under previously reported conditions. The SEM and X-ray diffraction measurements showed that the exfoliated single-layer Ti3C2Tx MXenes were reconstructed to assembled large-domain layered films, enabling excellent macroscale elec. conductivity XPS confirmed the complete removal of residual Al atoms and the replacement of surface fluorine atoms with hydroxy groups. Using the exfoliated dispersion, a flexible transparent conductive film was formed and demonstrated in an elec. application. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Synthetic Route of C4H12ClN).
Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Synthetic Route of C4H12ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics