Palladium-Catalyzed Cascade Deboronation/Regioselective B-P Coupling of closo-Carboranes was written by Yang, Ziyi;Sun, Chaofan;Wei, Xing;Lu, Jian;Lu, Ju-You. And the article was included in ChemCatChem in 2022.Related Products of 75-57-0 The following contents are mentioned in the article:
A cascade deboronation/regioselective B-P coupling of closo-carboranes is disclosed using a combination of palladium catalysts and nitrogen or phosphine-containing directing groups. Unsym. C-substituted closo-carboranes, including C-monosubstituted and unsym. 1,2-disubstituted closo-carboranes, are tolerated. Select closo-carboranes bearing other directing groups, such as benzoxazole, and diphenylphosphine, are compatible substrates for this reaction. Phosphine and arsenic can be utilized as effective coupling partners. Furthermore, a catalytic amount of palladium salt mediates the regioselective B-H activation process. Readily available closo-carboranes as the starting materials for direct one-pot synthesis of functionalized nido-carboranes and the in-situ formation of nido-carborane intermediates without purification are important features in terms of practical applications. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Related Products of 75-57-0).
Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Related Products of 75-57-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics