Additive effects of lithium halides on the tensile and rheological properties of poly(methyl methacrylate) was written by Ito, Asae;Shin, Arisa;Nitta, Koh-hei. And the article was included in Polymer Journal (Tokyo, Japan) in 2022.Electric Literature of ClLi The following contents are mentioned in the article:
Lithium halides are easily dispersed in poly(Me methacrylate) (PMMA) and lead to strong phys. crosslinking with PMMA. We investigated the addnl. effects of various lithium halides, such as LiCl, LiBr, and LiI salts, on the rheol. and mech. properties of PMMA. The salts were homogeneously dispersed in the PMMA matrix, and the flow zone expanded owing to the pinning effects of the molten PMMA chains as the anion size increased. Furthermore, the brittleness of the PMMA solids doped with LiX (X = Cl, Br, and I) was analyzed using the Griffith theory, which suggested that the stress concentration around the salts in the PMMA matrix leads to the initiation of macroscopic fractures. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Electric Literature of ClLi
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics