Greening Oxidation Catalysis: Water as a Solvent for Efficient Alkene Epoxidation over a Titanosilicate/H2O2 System was written by Yu, Yunkai;Fang, Nan;Chen, Zhen;Liu, Dongxu;Liu, Yueming;He, Mingyuan. And the article was included in ACS Sustainable Chemistry & Engineering in 2022.Recommanded Product: Lithium chloride The following contents are mentioned in the article:
Herein, we disclose the application of water (H2O) solvent in titanosilicate-catalyzed epoxidation of alkenes. A highly efficient H2O-solvent propylene epoxidation system (Ti-MWW/H2O/H2O2/propylene/K+) was achieved, possessing high activity, selectivity, and stability. Our investigation shows that this excellent catalytic performance is ascribed to the structure variation of H2O induced by K+. The superior H2O structure is the one that donates two and accepts one hydrogen bond (HB), which is known as the “DDA” H2O structure. The current report benefits sustainable applications in titanosilicate-catalyzed alkene epoxidation and conforms to the principles of green chem. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: Lithium chloride).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Recommanded Product: Lithium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics