Differentiating C-Br and C-Cl Bond Activation by Using Solvent Polarity: Applications to Orthogonal Alkyl-Alkyl Negishi Reactions was written by Hadei, Niloufar;Achonduh, George T.;Valente, Cory;O’Brien, Christopher J.;Organ, Michael G.. And the article was included in Angewandte Chemie, International Edition in 2011.SDS of cas: 6294-17-3 The following contents are mentioned in the article:
Orthogonal reactivity of bifunctional or unactivated bromochloroalkanes was observed in a double Negishi alkyl-alkyl cross-coupling reaction. This was made possible by a relatively simple solvent polarity trigger, lending itself to a one-pot approach. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3SDS of cas: 6294-17-3).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 6294-17-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics