Bissot, T. C. published the artcileThe reaction of O-methylhydroxylamine and its N-methyl derivatives with diborane, Product Details of C5H10Cl3O3P, the publication is Journal of the American Chemical Society (1958), 1868-74, database is CAplus.
B2H6 (I) reacted with MeONH2 (II) in Et2O at -112° to form MeONH2BH3 (III), m. 55°. Hydrolysis of III with dilute HCl gave 93% of the original II, and all 3 of the hydridic H was recovered; hydrolysis with 50% KOH at 100° gave reduction of II to NH3 and only 2/3 of the hydridic H was recovered. No reduction was observed when pure II was heated with 50% KOH. I reacted with MeONHMe (IV), with or without Et2O, to give MeONHMeBH3 (V), m. -23 to -21°. I reacted with NMe3 at 0° to give an 86% yield Me3NBH3 (VI). Acid hydrolysis of V gave H3BO3 and the salt of IV; basic hydrolysis gave 27% MeNH2 and other amines. Pure IV was unaffected by 50% KOH at 100°. Only 2/3 of the hydridic H of V was obtained by hydrolysis. I and MeONMe2 (VII) gave MeONMe2BH3 (VIII), m. -16.5 to -16.0°, vapor pressure 3.8 mm. at 25°. VIII and NMe3 reacted to regenerate 98% of the original VII. Basic hydrolysis of VIII gave 92% of the original VII and 90% of the hydridic H. III, V, VIII lost H on standing; 50% decomposition in 24 hrs. required temperatures of 55, 65, and 90°, resp. Reaction of III with BF3 in Et2O at 0° did not produce I and H evolution increased. Reaction of III with NMe3 gave 22% VI; H loss was again increased. NH3 had a similar effect. The pyrolysis of III, V, and VIII is discussed, and mechanisms for H loss and amine reduction during basis hydrolysis are suggested. When I reacted with II containing NH3 in Et2O, the etherate of H2NB2H5 (IX) was obtained. Pure IX was obtained by complexing the Et2O with AlCl3 or BF3.
Journal of the American Chemical Society published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Product Details of C5H10Cl3O3P.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics