Burn, A. J.’s team published research in Chemistry & Industry (London, United Kingdom) in | CAS: 866-23-9

Chemistry & Industry (London, United Kingdom) published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Safety of Diethyltrichloromethylphosphonate.

Burn, A. J. published the artcileA new oxidation of trialkyl phosphites, Safety of Diethyltrichloromethylphosphonate, the publication is Chemistry & Industry (London, United Kingdom) (1963), 736-7, database is CAplus.

cf. CA 56, 3508h. Reactions of (RO)3P and R’OH(R = Et, Bu, and allyl, and R’ = Et, Bu, tert-Bu, and allyl) with CCl4 or BrCCl3 to yield (RO)3PO and phosphorylation products of the alcs. are summarized. By suitable choice of phosphite and alc., the reaction provides a useful method of oxidation of phosphites or phosphorylation of alcs. The reaction proceeds by a radical-chain process involving solvolysis of an intermediate quasiphosphonium derivative, [(RO)3PCCl3]+Cl–.

Chemistry & Industry (London, United Kingdom) published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Safety of Diethyltrichloromethylphosphonate.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics