Freidlina, R. Kh. published the artcileThermal telomerization of olefins with silanes, Application In Synthesis of 14799-94-1, the publication is Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (1960), 662-8, database is CAplus.
cf. CA 52, 6165d. Heating 11.5 g. MeSiHCl2 and 4.3 g. C2H4 in an ampul in an autoclave 3 hrs. at 320-40° gave mixed MeEtSiCl2 and MeBuSiCl2 in yields of 42-80% and 17-28%, resp. The use of a bare steel autoclave tended to lower the yield of MeEtSiCl2 and raise that of BuMeSiCl2. Similarly, Ph3SiH and C2H4 in hexane 12 hrs. at 300° gave Ph3SiEt, m. 68-70°, and Ph3SiBu, m. 81-2°, along with some (Ph3Si)2O, m. 224°. Reaction of MeSiHCl2 and propylene in the presence of a catalytic amount of H2PtCl6 in iso-PrOH in 1 hr. at room temperature gave MePrSiCl2, which with MeMgBr gave known Me3SiPr. In the telomerization of MeSiHCl2 with C2H4 at 300°, the increased proportion of the olefin tended to lower steadily the yield of MeSiCl2Et and MeSiCl2(CH2CH2)2H, while the yield of MeSiCl2(CH2CH2)3H remained substantially constant and that of MeSiCl2(CH2CH2)3H rose rapidly. Elevation of the temperature from 285° to 350° increased the yield of MeSiCl2Et and decreased that of telomers with n over 3, while the intermediate telomer yield remained substantially constant
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C7H16Cl2Si, Application In Synthesis of 14799-94-1.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
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