Braunstein, Pierre published the artcileCarbonyl clusters with a capping methylidyne phosphonate ligand. Crystal structure of [Co3(CO)9{η1-μ3-[CP(O)(OEt)2]}], Application In Synthesis of 866-23-9, the publication is Journal of Organometallic Chemistry (1997), 541(1-2), 417-422, database is CAplus.
The bridging methylidyne clusters [Co3(CO)9{η1-μ3-[CP(O)(OR)2]}] (1, R = Et; 3, R = SiMe3) with α-phosphoryl substituents were synthesized by reaction of Cl3CP(O)(OR)2 with Co2(CO)8, followed by protonation. Cluster 3 was also obtained by the reaction of 1 with Me3SiBr. The structure of 1 was determined by x-ray crystallog. The donor properties of the P:O function toward Lewis acids such as [Cp2MCl]+ (M = Ti, Zr) were used to assemble early-late metal systems.
Journal of Organometallic Chemistry published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Application In Synthesis of 866-23-9.
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