Cao, Chuntao published the artcileReactions of Organosilanes with Silica Surfaces in Carbon Dioxide, Formula: C9H20Cl2Si, the publication is Langmuir (2001), 17(3), 757-761, database is CAplus.
Silylation reactions using liquid and supercritical CO2 as the solvent were performed on both single surface (silicon wafers) and nanoporous (silica gel) silica samples. The alkylsilyl monolayers formed on single surfaces were characterized by wettability, ellipsometry, and XPS. Modified nanoporous silica samples were analyzed by chem. anal. A range of different silanes including monochloro-, dichloro-, trichloro-, and dimethylamino-silanes was examined The results indicate that dense carbon dioxide is a good solvent for silylation reactions, comparable or better than most solvents. Compared with the optimum conditions for silylation at solid-liquid interfaces, reactions in carbon dioxide are faster, although maximum bonding densities are slightly lower.
Langmuir published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Formula: C9H20Cl2Si.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics