Kang, Seung-Hyun published the artcilePhosphonium Chloride-Catalyzed Dehydrochlorinative Coupling Reactions of Alkyl Halides with Hydridochlorosilanes, Name: Dichloro(hexyl)(methyl)silane, the publication is Organometallics (2003), 22(3), 529-534, database is CAplus.
The dehydrochlorinative Si-C coupling reactions of various primary and secondary alkyl chlorides with hydridochlorosilanes in the presence of tetrabutylphosphonium chloride as catalyst gave the coupling products with elimination of HCl as a gas. For example, RCl (R = CH2C6H4X-p; X = H, Cl, F, Me, MeO), when coupled with HSiCl3 in the presence of catalytic amounts of phosphonium salts [Bu4Y]Z (Y = P, N; Z = Cl, Br, I) gave RSiCl3 (R = same as above) in 80-96% yields. Coupling reactions of activated alkyl chlorides such as benzyl chlorides proceeded at 130°, while unactivated organic chlorides such as silylalkyl chlorides and secondary alkyl chlorides required higher reaction temperatures of 150 or 170° and longer reaction times. Primary alkyl chlorides reacted with trichlorosilane (1) to give coupling products in good to excellent yields, but secondary alkyl chlorides reacted at a slower rate and gave lower yields of products. Coupling reactions with methyldichlorosilane instead of 1 proceeded at slower rates and gave lower yields of products.
Organometallics published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C7H16Cl2Si, Name: Dichloro(hexyl)(methyl)silane.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics