Nesmeyanov, A. N. published the artcileThermal telomerization of methyldichlorosilane with olefins, Recommanded Product: Dichloro(methyl)(octyl)silane, the publication is Doklady Akademii Nauk SSSR (1957), 271-2, database is CAplus.
Heating 123 g. MeSiHCl2 2 hrs. in a steel autoclave with C2H4 to 260° and a final pressure of 560 atm. gave 80% conversion to telomerization products MeSiCl2(CH2CH2)nH, with n = 1-6, as follows (n, % yield, b.p., nD20, and d20 shown): 1, 23.6, b. 100°, -, -; 2, 25.6, b. 147-8°, 1.4312, 1.0427; 3, 17.7, b32 91°, 1.4390, 0.9931; 4, 13.4, b6 94° 1.4440, 0.9761; 5, 4.7, b3 111-14°, 1.4490, 0.9600; 6, 3.8, b3 124-7°, 1.4532, 0.9552. About 8.5% undescribed higher telomers were also formed. A similar reaction of MeSiHCl2 and C3H6 was run 3 hrs. at 260-75° and 100 atm. maximum pressure yielded from 151 g. MeSiHCl2, 216 g. products giving MeSiCl2(C3H6)nH (n shown) as follows: 1, 49, b. 123-4°, 1.4240, -; 2, 26.2, b32 82°, 1.4400, -; 3, 3.9, b2 80-2°, 1.4540, -; 10% undescribed higher telomers.
Doklady Akademii Nauk SSSR published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Recommanded Product: Dichloro(methyl)(octyl)silane.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
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