Steinbach, J. published the artcileReaction of the two-component system trialkyl phosphite/carbon tetrachloride with nucleophiles containing hydrogen. 2. Reaction with ammonia and amines, Name: Diethyltrichloromethylphosphonate, the publication is Zeitschrift fuer Anorganische und Allgemeine Chemie (1985), 180-6, database is CAplus.
RNH2 (R = H, Pr, Bu, PhCH2, Ph) reacted 1:1 with (R1O)3P (R1 = Et, Bu) and CCl4 to give (R1O)2P(O)NHR. If excess RNH2 was used, R1OP(O)(NHR)2 and OP(NHR)3 also formed. The reaction of (R1O)3P/CCl4 in the presence of secondary and tertiary amines gave (R1O)2P(O)CCl3, which reacted with the amine to give [Cl3CP(O)(O–)(OR1)][+NRR2R3R4].
Zeitschrift fuer Anorganische und Allgemeine Chemie published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C14H10O4S2, Name: Diethyltrichloromethylphosphonate.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics