Wu, Dunqi published the artcileCopper-Catalyzed Enantioselective Radical Chlorination of Alkenes, Recommanded Product: 2-Chloro-4-methylphenylboronic acid, the publication is ACS Catalysis (2022), 12(9), 5284-5291, database is CAplus.
In this report, authors reviewed a copper-catalyzed asym. atom transfer radical addition (ATRA) reaction, which remains a great challenge since the discovery of racemic ATRA in the 1940s. This enantioselective radical chlorination of acrylamides was developed, where three reagents, including Togni-I and TMSCl, PhICF3Cl, and CX3SO2Cl, were employed as the radical sources and chlorine source, affording a series of chlorinated carbon-centered quaternary compounds in good yields with excellent enantioselectivity. Notably, the well-designed bulky chiral ligand plays a key role in the successful enantioselective radical chlorination process.
ACS Catalysis published new progress about 145349-62-8. 145349-62-8 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids, name is 2-Chloro-4-methylphenylboronic acid, and the molecular formula is C7H7IN2O, Recommanded Product: 2-Chloro-4-methylphenylboronic acid.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics