Yamamoto, Keiji’s team published research in Journal of Organometallic Chemistry in 28 | CAS: 14799-94-1

Journal of Organometallic Chemistry published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C11H16BNO2, Product Details of C7H16Cl2Si.

Yamamoto, Keiji published the artcileInteraction of silanes with bis(triphenylphosphine)ethyleneplatinum(O); hydrosilylation of olefins with this complex, Product Details of C7H16Cl2Si, the publication is Journal of Organometallic Chemistry (1971), 28(3), C37-C38, database is CAplus.

Reaction of 1-hexene with MeCl2SiH in the presence of (Ph3P)2Pt(C2H4) (I) gave n-C6H13Si-MeCl2 in quant. yield via the intermediacy of (Ph3P)2PtH(SiMeCl2). In the absence of olefin, (Ph3P)2Pt(SiMeCl2)2 was isolated. I and HSiCl3 gave only (Ph3P)2Pt(SiCl3)2. Hydrosilylation of 1-hexene and Me3SiCH:CH2 was catalyzed by the complexes of I with (EtO)2MeSiH, Me2ClSiH, Me3SiH, or Me3EtSiH; the stability of such complexes decreased in the order SiCl3 > SiMeCl2 > SiMe3. I, MeCl2SiH, and 1,3-butadiene gave 1,2-, 1,4-, and dihydrosilylation products, but diaddn. was favored with isoprene.

Journal of Organometallic Chemistry published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C11H16BNO2, Product Details of C7H16Cl2Si.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics