Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl was written by Bluemke, Tobias D.;Piller, Fabian M.;Knochel, Paul. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2010.COA of Formula: C6H12BrCl The following contents are mentioned in the article:
Alkyl bromides bearing various functional groups are smoothly converted to functionalized alkylzinc reagents by the direct insertion of magnesium in the presence of LiCl and ZnCl2. These organozinc derivatives are used in situ for palladium-catalyzed cross-coupling reactions and additions to electrophiles such as aroyl chlorides, allyl bromides, and sulfonothioates. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3COA of Formula: C6H12BrCl).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.COA of Formula: C6H12BrCl
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics