Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction was written by Bulygina, Ludmila A.;Khrushcheva, Natalya S.;Lyssenko, Konstantin A.;Peregudov, Alexander S.. And the article was included in Mendeleev Communications in 2022.Safety of Sodium tetrachloropalladate(II) The following contents are mentioned in the article:
New bicyclic unsym. CNN Pd 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8-dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclo-palladation with Li2PdCl4 or Na2PdCl4 and NaOAc in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Safety of Sodium tetrachloropalladate(II)).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Safety of Sodium tetrachloropalladate(II)
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics