Photopromoted carbonylation of dihaloalkanes with methyl formate was written by Hu, Yao-yun;Jia, Ying-ping;Cui, Ying-na;Yin, Jing-mei. And the article was included in Liaoning Keji Daxue Xuebao in 2011.Electric Literature of C6H12BrCl The following contents are mentioned in the article:
The photopromoted carbonylation of dihaloalkanes with Me formate catalyzed by cobalt and copper salts catalysts is studied under ambient conditions. The results indicated that the single carbonylation product of 1,6-dibromohexane and 1-bromo-6-chlorohexane occurred. The corresponding mono-carbonylated products Br(CH2)6CO2CH3 and Cl(CH2)6CO2CH3 are obtained. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Electric Literature of C6H12BrCl).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of C6H12BrCl
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics