Cross-coupling reaction of alkyl halides with alkyl Grignard reagents catalyzed by Cp-iron complexes in the presence of 1,3-butadiene was written by Iwasaki, Takanori;Shimizu, Ryohei;Imanishi, Reiko;Kuniyasu, Hitoshi;Kambe, Nobuaki. And the article was included in Chemistry Letters in 2018.Formula: C6H12BrCl The following contents are mentioned in the article:
Iron-catalyzed cross-coupling reaction of alkyl halides with alkyl Grignard reagents by the combined use of cyclopentadienyl ligand and 1,3-butadiene additive was described. The reaction smoothly proceeded at room temperature using unactivated alkyl bromides and fluorides via non-radical mechanism, which was in sharp contrast with hitherto known Fe-catalyzed cross-coupling reactions of alkyl halides. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Formula: C6H12BrCl
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics