Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration was written by Jiang, Jing;Hu, Ying;Cai, Xin;Wang, Liudi;Hu, Yanwei;Chen, Shaohua;Zhang, Shilei;Zhang, Yinan. And the article was included in Organic & Biomolecular Chemistry in 2018.Safety of 1-Bromo-6-chlorohexane The following contents are mentioned in the article:
An effective dehydrochlorination of bis(phenylsulfonyl)alkanes to prepare alkene building blocks was developed. The elimination together with double bond migration resulted in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chem. diversification represented an easy and straightforward access to a series of alkene building blocks. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Safety of 1-Bromo-6-chlorohexane).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Safety of 1-Bromo-6-chlorohexane
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics