Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3]– was written by Proehm, Patrick;Schwarze, Nico;Mueller, Carsten;Steinhauer, Simon;Beckers, Helmut;Rupf, Susanne M.;Riedel, Sebastian. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Reference of 75-57-0 The following contents are mentioned in the article:
The authors present the synthesis and characterization of the first non-classical Cl(I) polyinterhalide [NMe4][F(ClF)3] as well as the homologous polychloride [NPr3Me][Cl7]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl2, resp. Quantum-chem. studies predict an unexpected planar structure for the [F(ClF)3]– anion. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Reference of 75-57-0).
Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Reference of 75-57-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics