Homogeneous hydrogenation of saturated bicarbonate slurry to formates using multiphase catalysis was written by Rebreyend, Christophe;Pidko, Evgeny A.;Filonenko, Georgy A.. And the article was included in Green Chemistry in 2021.COA of Formula: C25H54ClN The following contents are mentioned in the article:
Formic acid and formate salts are key intermediates along the pathways for CO2 utilization and hydrogen storage. Herein we report a highly efficient multiphase catalytic system utilizing a ruthenium PNP pincer catalyst for converting supersaturated bicarbonate solutions and slurries to aqueous formate solutions up to 12 M in molarity. The biphasic catalytic system delivers turnover frequencies up to 73 000 h-1 and remains stable for up to 474 000 turnovers once reaction conditions are optimized. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3COA of Formula: C25H54ClN).
N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.COA of Formula: C25H54ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics