Oxochloroselenate(IV) with Incorporated {Cl2}: The Case of Strong Cl···Cl Halogen Bonding was written by Usoltsev, Andrey N.;Korobeynikov, Nikita A.;Kolesov, Boris A.;Novikov, Alexander S.;Abramov, Pavel A.;Sokolov, Maxim N.;Adonin, Sergey A.. And the article was included in Chemistry – A European Journal in 2021.Formula: C4H12ClN The following contents are mentioned in the article:
Reaction of SeO2, tetramethylammonium (TMA) chloride, aqueous HCl and Cl2 yields oxochloroselenate with incorporated Cl2 units, TMA3{[Se2O2Cl7](Cl2)}. The main feature of this compound is the strong (up to 3.5 kcal mol-1, according to DFT calculations) Cl···Cl bonding, which is also detected by Raman spectroscopy. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Formula: C4H12ClN).
Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: C4H12ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics