Photoexcited Direct Amination/Amidation of Inert Csp3-H Bonds via Tungsten-Nickel Catalytic Relay was written by Wang, Qing;Ni, Shengyang;Yu, Lei;Pan, Yi;Wang, Yi. And the article was included in ACS Catalysis in 2022.Application of 7447-41-8 The following contents are mentioned in the article:
Light alkanes are the most abundant resources in nature. It is of great significance to develop convenient methods to realize the conversion of alkanes to high value-added products. However, the examples of aliphatic amines derived from unactivated alkanes remain rare. This work describes a rapid construction of C(sp3)-N bonds from light alkanes with amine/amide electrophile reagents via high-valent tungsten and nickel catalysis in high efficiency. The photoexcited metal relay provides a powerful tool for the activation of inert sp3-hybridized C-H bonds and stabilization of C-Ni(III)-N intermediates. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 7447-41-8
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics