The Combination of Benzaldehyde and Nickel-Catalyzed Photoredox C(sp3)-H Alkylation/Arylation was written by Zhang, Lumin;Si, Xiaojia;Yang, Yangyang;Zimmer, Marc;Witzel, Sina;Sekine, Kohei;Rudolph, Matthias;Hashmi, A. Stephen K.. And the article was included in Angewandte Chemie, International Edition in 2019.Application of 6294-17-3 The following contents are mentioned in the article:
Herein the authors report a highly selective photoredox C(sp3)-H alkylation/arylation of ethers through the combination of a photoorganocatalyst (benzaldehyde) and a transition-metal catalyst (nickel). This method provides a simple and general strategy for the C(sp3)-H alkylation/arylation of ethers. A selective late-stage modification of (-)-ambroxide also was conducted to demonstrate the applicability of the method. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Application of 6294-17-3).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 6294-17-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics