A New Rhodium/Copper-Cocatalyzed C-H Oxidation for the Preparation of Isoquinolin-1-ones was written by Zhou, Zeng-Le;Liu, Yi-Lin;Song, Jian-Lan;Deng, Chen-Liang. And the article was included in Synthesis in 2016.Category: chlorides-buliding-blocks The following contents are mentioned in the article:
A new and efficient rhodium/copper-cocatalyzed C-H oxidation reaction of isoquinolinium N-amides was developed. In the presence of rhodium(II) acetate dimer, copper(II) chloride, a ligand and sodium tert-butoxide, a variety of isoquinolin-1-ones were prepared in moderate to good yields via ortho C-H oxidation This study involved multiple reactions and reactants, such as 5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3Category: chlorides-buliding-blocks).
5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics