Abhishek, Verma published the artcileMechanistic aspect of Iridium(III) catalyzed oxidation of ethylene glycol by Chloramine-T in aqueous acidic medium: a kinetic model, Formula: C7H13ClNNaO5S, the publication is G P Globalize Research Journal of Chemistry (2018), 1(2), 107-115, database is CAplus.
The kinetic investigation of homogeneously Ir(III) chloride catalyzed oxidation of Ethylene glycol by Chloramine- T [CAT] in perchloric acid medium has been carried out in the temperature range of 30 to 45°C. The reaction was carried out in the presence of mercuric acetate as a scavenger for chloride ion. The reaction exhibits first order kinetics with respect to the oxidant [CAT] and catalyst [Ir(III)] while zero order with respect to substrate, i.e., Ethylene glycol (EG) was observed The reaction shows negligible effect of [Hg(OAc)2], [H+] and ionic strength of the medium. Chloride ion pos. influenced the rate of reaction. The various activation parameters have been calculated from the rate measurements at different temperatures (30 to 45°C). The product of the reaction has been identified as the corresponding monocarboxylic acid. The reaction between Chloramine-T and Ethylene glycol in acid medium shows 2:1 stoichiometry. On the basis of kinetic studies, reaction stoichiometry and product anal., a suitable mechanism has been proposed and rate law has been derived.
G P Globalize Research Journal of Chemistry published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Formula: C7H13ClNNaO5S.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics