Darses, Benjamin published the artcileAsymmetric synthesis of amines through rhodium-catalyzed C-H amination with sulfonimidoylnitrenes, Quality Control of 7080-50-4, the publication is Synthesis (2013), 45(15), 2079-2087, database is CAplus.
An efficient asym. C-H amination of benzylic and allylic substrates, as well as of adamantane derivatives, through catalytic C-H insertion of a chiral nitrene is reported. The reaction involves a chiral rhodium(II) complex, an iodine(III) oxidant, and a sulfonimidamide as a nitrene precursor. Exptl. protocols for the preparation of the reagents and the catalytic nitrene are provided. The C-H amination can provide the corresponding amino derivatives on a gram scale. Various methods for the cleavage of the sulfonimidoyl group to give the corresponding tert-butoxycarbonyl- or acetyl-protected optically pure amines are also described.
Synthesis published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Quality Control of 7080-50-4.
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