Rezaeifard, Abdolreza published the artcileBenzyltributylammonium periodate as a novel and safe oxygen source for Mn-porphyrin catalyzed practical and highly selective oxygenation of hydrocarbons, SDS of cas: 23616-79-7, the publication is Polyhedron (2011), 30(13), 2303-2309, database is CAplus.
Benzyltributylammonium periodate (BzBu3NIO4) was prepared easily in high yield in neat water. The compound crystallized with two cations and two anions per asym. unit and a space group of Pna21 was determined by single-crystal x-ray diffraction. It was used practically in the clean and selective epoxidation of olefins and oxygenation of saturated hydrocarbons catalyzed by manganese (III) porphyrins in water/ethanol as a green media. The catalyst could be reused without noticeable loss of activity, and the oxidant’s byproduct (BzBu3NIO3) could also be reused. The efficiency of the oxidation system depends critically upon the steric hindrances and electronic structures of both the nitrogen donors and Mn-catalysts. Some evidences suggest the involvement of a high valent Mn-oxo species as well as a six-coordinate [(L)(Por)Mn-OIO3] complex in the oxidation reactions.
Polyhedron published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, SDS of cas: 23616-79-7.
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https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics