Zheng, Yuxin published the artcileRegiodivergent Desymmetrization Reaction of meso-Azabicycloheptene Providing Two Enantioenriched Structural Isomers, Recommanded Product: Sodium chloro(tosyl)amide trihydrate, the publication is Organic Letters, database is CAplus and MEDLINE.
A novel catalytic asym. reaction uses the regiodivergent desymmetrization of 7-tosyl-7-azabicyclo[4.1.0]hept-3-ene via allylic oxidation using a single chiral copper catalyst to produce two different, enantioenriched structural isomers in high optical purity starting from a single compound The enantioselectivity of the two structurally isomeric compounds was enriched to >99.5%ee after derivatization.
Organic Letters published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C26H26N4O7, Recommanded Product: Sodium chloro(tosyl)amide trihydrate.
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