Burkhard, C. A.’s team published research in Journal of the American Chemical Society in 69 | CAS: 14799-93-0

Burkhard, C. A. published the artcileAlkylation of hydrochlorosilanes, HPLC of Formula: 14799-93-0, the publication is Journal of the American Chemical Society (1947), 2687-9, database is CAplus.

HSiCl₃ adds with ease to olefinic double bonds in the presence of peroxides or ultraviolet light; the reaction appears to proceed exclusively by the addition of the SiH bond. In general, 0.5 or 0.75 mole olefin was used with 1 mole of the chlorosilane and 0.013-0.026 mole of peroxide (30% Ac₂O₂ in o-C₆H₄(CO₂Me)₂ used unless otherwise indicated); this mixture was heated 4-24 hrs. at 70-100°. 1-Pentene and HSiCl₃ give 73% AmSiCl₃, b. 166-9°, and MeHSiCl₂ gives 37% pentylmethyldichlorosilane, b. 164-8°. 2-Pentene and MeHSiCl₂ give 71% 2-pentylmethyldichlorosilane, b₁₀₀ 100°. Cyclohexene and HSiCl₃ give 64% cyclohexyltrichlorosilane, b. 199°; iso-C₄H₈ and HSiCl₃ (tert-Bu perbenzoate as catalyst) give iso-BuSiCl₃, b. 136°. CH₂:CHSiCl₃ (I) and HSiCl₃ give 19% (CH₂SiCl₃)₂, b. 199°; this results in 3% yield from C₂H₂ (Bz₂O₂ as catalyst), I being postulated as an intermediate. CH₂:CHCH₂SiCl₃ and HSiCl₃ give 83% 1,3-bis(trichlorosilyl)propane, b₂₀ 111°. HSiCl₃ (135 g.) and 78 g. uninhibited PhCH:CH₂, heated 4 hrs. at 100°, give 70 g. of a glassy solid; alc.-NaOH gives no H, indicating that Si-C bonds had been formed.

Journal of the American Chemical Society published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, HPLC of Formula: 14799-93-0.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics