Mciteka, Lulama P. published the artcileSynthesis of camphor-derived chiral auxiliaries and their application in asymmetric Morita-Baylis-Hillman reactions, Product Details of C10H15ClO3S, the publication is ARKIVOC (Gainesville, FL, United States) (2016), 151-163, database is CAplus.
N-Substituted 2-exo-hydroxybornyl-10-sulfonamides, prepared as potential chiral auxiliaries for use in asym. Morita-Baylis-Hillman (MBH) reactions, were treated with acryloyl chloride to afford the corresponding 2-exo-acrylate esters as MBH substrates. Reaction of selected 2-exo-acrylate ester substrates with pyridine-4-carbaldehyde and 6-methylpyridine-2-carbaldehyde in the presence of DABCO gave the expected MBH adducts in >91% yield and with diastereoselectivities of 7-33% d.e.
ARKIVOC (Gainesville, FL, United States) published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Product Details of C10H15ClO3S.
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