Balaraman, Kaluvu published the artcileOrganocatalytic Decarboxylative Cyanomethylation of Difluoromethyl and Trifluoromethyl Ketones, Computed Properties of 5860-95-7, the publication is Advanced Synthesis & Catalysis (2018), 360(24), 4705-4709, database is CAplus and MEDLINE.
An efficient organocatalytic method for the synthesis of difluoromethyl and trifluoromethyl substituted β-hydroxynitriles RC(OH)(CXF2)CH2CN (R = Ph, cyclohexyl, furan-2-yl, etc.; X = H, F) is introduced. The decarboxylative cyanomethylation of fluorinated ketones RC(O)CXF2 with readily available cyanoacetic acid gives a variety of tertiary alcs. in high yields and without concomitant water elimination. The reaction occurs in the presence of catalytic amounts of triethylamine, and can be upscaled and applied to chlorofluoromethyl ketones and difluoromethyl ketimines.
Advanced Synthesis & Catalysis published new progress about 5860-95-7. 5860-95-7 belongs to chlorides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Chloride,Benzene,Ketone, name is 1-(2-Chlorophenyl)-2,2,2-trifluoroethanone, and the molecular formula is C8H4ClF3O, Computed Properties of 5860-95-7.
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Chlorides – an overview | ScienceDirect Topics