Bao, Zhi-Peng published the artcileA novel construction of acetamides from rhodium-catalyzed aminocarbonylation of DMC with nitro compounds, Synthetic Route of 21286-54-4, the publication is Chemical Communications (Cambridge, United Kingdom) (2021), 57(15), 1955-1958, database is CAplus and MEDLINE.
Di-Me carbonate (DMC), an environment-friendly compound prepared from CO2, shows diverse reactivities. In this communication, construction of acetamides CH3C(O)NHR (R = n-Pr, cyclohexyl, naphthalen-1-yl, 2H-1,3-benzodioxol-5-yl, quinolin-8-yl, etc.) by an efficient procedure using DMC as both a C1 building block and solvent in the aminocarbonylation reaction with nitro compounds RNO2 has been developed. W(CO)6 acts both a CO source and a reductant.
Chemical Communications (Cambridge, United Kingdom) published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Synthetic Route of 21286-54-4.
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