Dulski, Mateusz published the artcileDifferent route of hydroxide incorporation and thermal stability of new type of water clathrate: X-ray single crystal and Raman investigation, Safety of Sodium chloro(tosyl)amide trihydrate, the publication is Scientific Reports (2017), 7(1), 1-9, database is CAplus and MEDLINE.
Chlormayenite Ca12Al14O32[4Cl2] (-vacancy) is partially hydrated micro porouss mineral with hydroxide groups situated at various crystallog. sites. There are few mechanisms describing its hydration. The first one assumes Cl– substitution by OH– at the center of the structural cages (W-site). The second one determines the converting a T1O4 tetrahedron to a T1O3(OH)3 octahedron due to the replacement of oxygen at the O2 site by three OH-groups according to the scheme: (O2O2- + WCl–) → 3 × O2aOH. The third mechanism, not considered so far in the case of zeolite-like minerals, includes the hydroxide incorporation in form of hydrogarnet defect due to the arrangement of tetrahedral (OH)4 in vacant cages. This yields a strong hydrated phase containing even up to 35% of water more than in any currently known mineral applicable to Portland cement. Moreover, water mols. present in different structural cages are stable up to 355 K while dehydroxylation linked to the gradual loss of only 8% of OH– groups according to 3O2aOH– → O2O2- +WOH– + gH2O occurs at temperature range from 355 K to 598 K.
Scientific Reports published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Safety of Sodium chloro(tosyl)amide trihydrate.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics