Gramstad, Thor’s team published research in Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy in 28 | CAS: 866-23-9

Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Application In Synthesis of 866-23-9.

Gramstad, Thor published the artcileHydrogen bonding. XXIII. Interaction of chloroform with various phosphoryl compounds. Higuchi plot. Solvent effect, Application In Synthesis of 866-23-9, the publication is Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (1972), 28(7), 1405-13, database is CAplus.

The Higuchi plot has been used to evaluate the Kassocn., ΔH, and ΔS values for the 1:1 association between CHCl3 and 6 phosphoryl compounds ΔH forms a linear relation with the change in NMR chem. shift, Δδx, and with ir frequency shift, ΔvC-D measured with CDCl3. Also a linear relation exists between Taft σ* constant and ΔH. On replacing CCl4 with cyclohexane as solvent, the Kassocn. and ΔH values are increased considerably.

Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Application In Synthesis of 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics