Gramstad, Thor published the artcileHydrogen bonding. XXVI. Proton NMR studies of hydrogen bonding between thiophenol and phosphoryl compounds. Hiquchi plot. Solvent effect, SDS of cas: 866-23-9, the publication is Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (1974), 30A(11), 2121-31, database is CAplus.
The association constants, (Ka), entropy, and enthalpy (ΔH) for the H-bonding of PhSH with 6 phosphoryl compounds, e.g., (EtO)2P(O)CCl3, were determined using the Hiquchi plot. ΔH and log Ka were both linearly dependent on the change in NMR chem. shift, Δδx, and with ir frequency shift δυSH, and δΔx and σν were linearly related. On going from CCl4 to cyclohexane solvent Ka and -δH were greatly increased whereas δx and δΔx were considerably decreased. A relation between the energy changes between S-H and C-H and S-H and O-H proton donors was established.
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, SDS of cas: 866-23-9.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
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