Koppenhoefer, B. published the artcileBackbone modification of Chirasil-Val: effect of nonpolar side chains on enantiomer separation in gas chromatography, Computed Properties of 14799-93-0, the publication is Chromatographia (1995), 40(11/12), 718-23, database is CAplus.
The polysiloxane backbone of the gas chromatog. phase Chirasil-Val has been modified by replacing one Me group per dialkylsiloxy unit by pentyl and hexyl groups, resp. The new phases offer the advantage of reduced polarities and softening points, while the separation factors (α) of enantiomeric pairs of N,O-trifluoroacetyl amino acid Pr esters show small but intriguing deviations from those determined on Chirasil-Val.
Chromatographia published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Computed Properties of 14799-93-0.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics