Roszkowski, Piotr published the artcileNew N,N-diamine ligands derived from (-)-menthol and their application in the asymmetric transfer hydrogenation, Recommanded Product: Sodium chloro(tosyl)amide trihydrate, the publication is Tetrahedron: Asymmetry (2017), 28(4), 532-538, database is CAplus.
Natural (-)-menthol was applied to construction of mono-N-tosylated-1,2-diamine derivatives The O-tosylation and elimination of the tosylate of the menthol intermediate led to trans-p-menth-2-ene. The unsaturated menth-2-ene was next transformed into a mixture of N-tosylaziridines, which upon reaction with sodium azide gave four isomeric azides. The reduction of the formed tosylazides on Pd/C gave new chiral mono-N-tosylated-1,2-diamines, which were used as ligands in the asym. transfer hydrogenation protocol on aromatic ketones and endocyclic imine.
Tetrahedron: Asymmetry published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C7H13ClNNaO5S, Recommanded Product: Sodium chloro(tosyl)amide trihydrate.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics