Tan, Daniel A. published the artcileSynthesis of Distally-Bridged Chiral Resorcinarene Crowns, Category: chlorides-buliding-blocks, the publication is European Journal of Organic Chemistry (2020), 2020(35), 5695-5708, database is CAplus.
Our interest in the potential of chiral tetramethoxy-resorcinarene as agents for chiral recognition has led us to synthesize twelve distally-bridged chiral resorcinarene crowns. The fascinating architecture of these partially-enclosed chiral basket mols. is evident in the solid-state structures which have been determined by single-crystal X-ray crystallog. Moreover, the enantiomers of these chiral resorcinarene crowns have been resolved via diastereomeric resolution, with the absolute configuration of the diastereomers being determined by X-ray crystallog. This work enables further exploration of these enantio-pure chiral baskets as possible chiral resolving agents.
European Journal of Organic Chemistry published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C5H4N4, Category: chlorides-buliding-blocks.
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