Tsoung, Jennifer published the artcileMulticomponent-Multicatalyst Reactions (MC)2R: Efficient Dibenzazepine Synthesis, Quality Control of 145349-62-8, the publication is Organic Letters (2014), 16(1), 110-113, database is CAplus and MEDLINE.
A RhI/Pd0 catalyst system was applied to the multicomponent synthesis of azadibenzazepines from vinylpyridines, arylboronic acids, and amines in a domino process with no intermediate isolation or purification E.g., a combination of 3-chloro-5-(trifluoromethyl)-2-vinylpyridine, 2-chlorophenylboronic acid, and p-toluidine was added to a catalyst solution containing Pd precatalyst (I, L = RuPhos), XPhos, and [Rh(cod)OH]2 to give a 67% yield of 5-(p-tolyl)-3-(trifluoromethyl)-10,11-dihydro-5H-benzo[b]pyrido[2,3-f]azepine (II).
Organic Letters published new progress about 145349-62-8. 145349-62-8 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids, name is 2-Chloro-4-methylphenylboronic acid, and the molecular formula is C5H6BNO2, Quality Control of 145349-62-8.
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