Belyakova, Z. V. published the artcileEffect of catalysts on the reaction of allyl esters with hydrosilanes, Name: Dichloro(methyl)(octyl)silane, the publication is Russian Journal of General Chemistry (2010), 80(4), 728-733, database is CAplus.
Hydrosilylation of allyl esters XOCH2CH:CH2 (X = MeCO, CF3CO, C3F7CO, CH2:C(Me)CO), PhOCH2CH:CH2 and ClCH2CH:CH2 with hydrosilanes HSiCl3, HSi(OEt)3 and HSiMeCl2 in the presence of Speier’s catalyst, Speier’s catalyst with additives, and of various Ni compounds was studied. The catalytic hydrosilylation reaction in the presence of the Speier catalyst is accompanied by reductions Additives to the Speier catalyst (vinyltriethoxysilane, allyl acetate and trifluoroacetate) suppress the reduction reaction considerably. E.g., hydrosilylation of allyl methacrylate with HSiCl3 in the presence of Speier’s catalyst gave CH2:C(Me)CO2CH2CH2CH2SiCl3 in 67% yield and a ratio of 5.55 of the addition product to the reduction product. The same reaction in the presence of Speier’s catalyst and vinyltriethoxysilane afforded CH2:C(Me)CO2CH2CH2CH2SiCl3 in 87% yield and a ratio of 114.1 of the addition product to the reduction product. In the presence of the studied Ni compounds mainly reduction and isomerization reactions of allyl Ph ether occurred. The best Ni catalysts for hydrosilylation were mixtures of NiCl2 or Ni(acac)2 with phosphine oxides. In contrast to allyl Ph ether, the hydrosilylation of simple olefins proceeds easier. E.g., hydrosilylation of 1-heptene with HSiCl3 in the presence of NiCl2 and (octyl)3P:O gives the hydrosilylation product trichloroheptylsilane in 94% yield in the reaction mixture
Russian Journal of General Chemistry published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Name: Dichloro(methyl)(octyl)silane.
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