Fu, Ying published the artcileA visible-light photoinduced charge-transfer complex promoted the ring opening of N-alkyl-4-piperidinols, Safety of 4-Chloro-3-(trifluoromethyl)benzenesulfonyl Chloride, the publication is Green Chemistry (2020), 22(7), 2264-2269, database is CAplus.
A visible-light photoinduced ring opening of N-alkyl-4-piperidinols under mild conditions was achieved. The reaction sequence involved a visible-light-induced charge-transfer complex, which promoted the S-Cl bond cleavage of sulfonyl chlorides. The generated sulfonyl radical further reacts with N-alkyl-4-piperidinol cation radicals to achieve C-N and C-C bond cleavages to yield homoallylamine products.
Green Chemistry published new progress about 32333-53-2. 32333-53-2 belongs to chlorides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Chloride,Sulfonyl chlorides,Benzene, name is 4-Chloro-3-(trifluoromethyl)benzenesulfonyl Chloride, and the molecular formula is C7H3Cl2F3O2S, Safety of 4-Chloro-3-(trifluoromethyl)benzenesulfonyl Chloride.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics