Le Menn, J. C. published the artcileThe methoxy-iminium cation issued from DMF in organic electrosynthesis: an electrophile and a supporting-electrolyte cation, Related Products of chlorides-buliding-blocks, the publication is Electrochimica Acta (1991), 36(5-6), 819-23, database is CAplus.
Electrophilic reactivity of the methoxy-iminium cation (I), resulting from the reaction between dimethyl sulfate and DMF, has been investigated towards electrogenerated carbanions produced by electroreduction of activated polyhalo compounds Controlled potential reduction of di-Et trichloromethylphosphonate (II) in the presence of three equivalent of I in DMF leads to the expected adduct (EtO)2P(O)CCl2-CH(NMe2)OMe (60% yield). Galvanostatic reduction of II in the presence of two equivalent of I leads to mixtures of the enamine (EtO)2P(O)CCl=CH(NM2) and the ynamine (EtO)2P(O)CCNMe2; when acetic acid is added, a mixture of the enamine and the enol-ether (EtO)2P(O)CCl=CH(OMe) is obtained. Lastly, the enamine can be synthesized with a 80% yield by electroreducing II in the presence of four equivalent of I in the same way, enamines (MeO2C)2C=CH(NMe2) (40% yield) and (EtO2C)CCl=CH(NMe2) (50% yield) are obtained from the electroreduction of di-Me dibromomalonate or Et trichloroacetate, resp.
Electrochimica Acta published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Related Products of chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics