Miwa, Takuya published the artcileRhodium-Catalyzed Synthesis of Silicon-Bridged 1,2-Dialkenylbenzenes via 1,4-Rhodium Migration, COA of Formula: C7H8BClO2, the publication is Organic Letters (2019), 21(6), 1627-1631, database is CAplus and MEDLINE.
An efficient synthesis of 1,3-dialkylidene-2,3-dihydro-1H-benzo[c]siloles, a new type of Si-bridged π-conjugated compounds, was developed from a simple substrate combination of dialkynylsilanes and arylboronic acids under Rh catalysis through the use of 1,4-Rh migration. The reaction pathway was probed by D-labeling experiments, and the use of o-tolylboronic acids gave 6-membered silacycles via 1,5-Rh migration.
Organic Letters published new progress about 209919-30-2. 209919-30-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids,Boronic acid and ester, name is 4-Chloro-2-methylphenylboronic acid, and the molecular formula is C7H8BClO2, COA of Formula: C7H8BClO2.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics