Yakubenko, Artyom A.’s team published research in Physical Chemistry Chemical Physics in 24 | CAS: 7080-50-4

Physical Chemistry Chemical Physics published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C9H20Cl2Si, Quality Control of 7080-50-4.

Yakubenko, Artyom A. published the artcileSelf-association of diphenylpnictoginic acids in solution and solid state: covalent vs. hydrogen bonding, Quality Control of 7080-50-4, the publication is Physical Chemistry Chemical Physics (2022), 24(13), 7882-7892, database is CAplus and MEDLINE.

Triphenylpnictogens were oxidized to access diphenylpnictioginic acids Ph2XOOH (X = P, As, Sb, Bi). Oxidation with chloramine-T does not lead to the cleavage of a C-pnictogen bond. The preliminary reductive cleavage with sodium in liquid ammonia followed by the oxidation with hydrogen peroxide was successfully used for the synthesis of diphenylphosphinic and diphenylarsinic acids. In solid state (by XRD), all diphenylpnictoginic acids form polymeric chains. Diphenylbismuthinic and diphenylantimonic acids form polymeric covalent adducts, while diphenylphosphinic and diphenylarsinic chains are associated through hydrogen bonding. Unlike diphenylphosphinic acid, diphenilarsinic acid forms two polymorphs of hydrogen-bonded infinite chains. In solution in a polar aprotic solvent diphenylarsinic acid, similarly to dimethylarsinic, forms hydrogen-bonded cyclic dimers together with a small amount of cyclic trimers.

Physical Chemistry Chemical Physics published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C9H20Cl2Si, Quality Control of 7080-50-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics