Kong, Xianqiang published the artcileManganese-Catalyzed ortho-C-H Amidation of Weakly Coordinating Aromatic Ketones, Product Details of C10H15ClO3S, the publication is Organic Letters (2018), 20(15), 4495-4498, database is CAplus and MEDLINE.
An efficient manganese-catalyzed ortho-C-H amidation of weakly coordinating aromatic ketones using the readily available sulfonyl azide as the amination reagent is developed. The key step is the ketone directed aromatic metalation using the in situ generated reactive Mn intermediate, MnMe(CO)5. This method offers excellent chem. yields, high regioselectivities, and good functional group tolerance.
Organic Letters published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Product Details of C10H15ClO3S.
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