Lai, J. S. published the artcilePreparation of sulfur ylide complexes of platinum by phase transfer catalysis, Application of trimethyloxosulphonium chloride, the publication is Journal of Organometallic Chemistry (1990), 393(3), 431-40, database is CAplus.
Various sulfur ylide complexes of Pt were prepared by the phase transfer catalysis (PTC). Thus, reaction of Pt(PR3)2Cl2 (R = Me, Ph) in CH2Cl2 with [S(O)(CH3)3]I under PTC/OH– conditions give complexes {Pt(PR3)2[(CH2)2S(O)(CH3)]}I, which contain a bidentate double sulfur ylide. With Pt(dppe)Cl2 [dppe = Ph2P(CH2)2PPh2] as starting material, a similar product was obtained. But when Pt(dppm)Cl2 [dppm = Ph2PCH2PPh2] was treated with [S(O)(CH3)3]Cl under PTC/OH– conditions, an unexpected product {Pt(PPh2CH3)(PPh2OH)[(CH2)2S(O)(CH3)]}Cl was obtained. This compound contains a bidentate double sulfur ylide and two unsym. phosphines resulting from the base hydrolysis of dppm. Compound {Pt(PPh3)2[(CH2)2S(O)(CH3)]}I, was subjected to an x-ray diffraction study.
Journal of Organometallic Chemistry published new progress about 5034-06-0. 5034-06-0 belongs to chlorides-buliding-blocks, auxiliary class Salt,Aliphatic hydrocarbon chain, name is trimethyloxosulphonium chloride, and the molecular formula is C3H9ClOS, Application of trimethyloxosulphonium chloride.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics